116735-70-7

Basic information

• Product Name: Benzenamine, 4-methoxy-N-[2-(phenylmethoxy)propylidene]-, (S)-
• CAS NO: 116735-70-7
• Molecular Formula: C17H19NO2
• Molecular Weight: 269.343
• Mol File: 116735-70-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-methoxy-N-[2-(phenylmethoxy)propylidene]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-methoxy-N-[2-(phenylmethoxy)propylidene]-, (S)-(116735-70-7)
• EPA Substance Registry System: Benzenamine, 4-methoxy-N-[2-(phenylmethoxy)propylidene]-, (S)-(116735-70-7)

Safety Data

• Hazardous Substances Data: 116735-70-7(Hazardous Substances Data)

Upstream product

• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 104-94-9 4-methoxy-aniline 
• 54783-72-1 ethyl (S)-2-(benzyloxy)propionate 
• 100-39-0 benzyl bromide 

Downstream Products

• 146860-89-1 (3S,4R)-3-Benzyloxy-4-((S)-1-benzyloxy-ethyl)-1-(4-methoxy-phenyl)-azetidin-2-one 
• 146860-96-0 (2S,3R,4S)-3-Benzoylamino-2,4-bis-benzyloxy-pentanoic acid methyl ester 
• 146860-99-3 (2S,3R,4S)-2,4-Bis-benzyloxy-3-isocyano-pentanoic acid methyl ester 
• 146860-95-9 (2S,3R,4S)-2,4-Bis-benzyloxy-3-formylamino-pentanoic acid methyl ester 
• 146860-93-7 (2S,3R,4S)-3-Amino-2,4-bis-benzyloxy-pentanoic acid methyl ester 
• 146861-00-9 (2S,4S)-2,4-Bis-benzyloxy-pentanoic acid methyl ester 
• 146860-91-5 (3S,4R)-3-Benzyloxy-4-((S)-1-benzyloxy-ethyl)-azetidin-2-one 

Relevant articles and documents

Synergistic substrate and catalyst effects in the addition of trimethylsilyl cyanide to imines derived from lactic acid

Trimethylsilylcyanide was added to various imines derived from (2S)-ethyl lactate in the presence of Lewis acids to provide both syn- and anti- β-hydroxy-α-aminonitrile stereoisomers. Syn-products were found to be the major in most instances, however, ant

Synthesis of β-lactams by condensation of titanium enolates of 2-pyridylthioesters with imines. Influence of the imine structure on the trans/cis stereoselectivity

The condensation of the titanium enolates of C-2 alkyl substituted 2-pyridylthioesters with imines affords β-lactams in trans/cis ratios that largely depend on the structure of the C-imine residue. Bulky and non-chelating heteroatom-containing groups lead to the formation of trans β-lactams, while sterically non-requiring or chelating groups favour the formation of the cis-products. On the basis of NMR evidences a rationale is proposed to account for the observed stereoselectivity.