1168207-69-9Relevant academic research and scientific papers
Reaction of n,n-dioxyenamines with anhydrides of carboxylic and sulfonic acids; A new method for the synthesis of a-hydroxyoxime derivatives
Tabolin, Andrey A.,Lesiv, Alexey V.,Ioffe, Sema L.
experimental part, p. 3099 - 3105 (2010/01/15)
The reactions of N,N-dioxyenamines with carboxylic and sulfonic acid anhydrides were investigated. A new method for the synthesis of a-hydroxyoxime derivatives via the reaction of N,N-dioxyenamines with trifluoroacetic anhydride is described.
Rearrangement of 3-alkylidene-2-siloxy-tetrahydro-1,2-oxazines (ASENA). A new approach toward the synthesis of 3-α-hydroxyalkyl-5,6-dihydro-4H-1,2-oxazines
Tabolin, Andrey A.,Lesiv, Alexey V.,Khomutova, Yulia A.,Nelyubina, Yulia V.,Ioffe, Sema L.
experimental part, p. 4578 - 4592 (2009/11/30)
A new approach toward the synthesis of 3-α-hydroxyalkyl-5,6-dihydro-4H-1,2-oxazines 1 from available 5,6-dihydro-4H-1,2-oxazine N-oxides 2 has been described. The key step of the process-the rearrangement of 3-alkiliden-2-siloxy-tetrahydro-1,2-oxazines 3 (ASENA)-was thoroughly investigated. Optimal experimental conditions were developed. A possible pathway of the ASENA rearrangement was proposed.
