116847-33-7Relevant academic research and scientific papers
Benzotriazol-1-yl-sulfonyl azide for diazotransfer and preparation of azidoacylbenzotriazoles
Katritzky, Alan R.,El Khatib, Mirna,Bolshakov, Oleg,Khelashvili, Levan,Steel, Peter J.
experimental part, p. 6532 - 6539 (2010/12/19)
Benzotriazol-1-yl-sulfonyl azide, a new crystalline, stable, and easily available diazotransfer reagent provides N-(α-azidoacyl)benzotriazoles convenient for N-, O-, C- and S-acylations. The efficient syntheses of various amides, azido protected peptides, esters, ketones and thioesters is reported together with a wide range of azides (including α-azido acids from α- amino acids in partially aqueous conditions) and diazo compounds.
New one-carbon degradative transformation of β-alkyl-β-azido alcohols
Fan, Qiu-Hua,Ni, Nan-Ting,Li, Qin,Zhang, Li-He,Ye, Xin-Shan
, p. 1007 - 1009 (2007/10/03)
A new transformation of 2-azido-1-hydroxy-containing compounds to nitriles with one carbon less than the starting materials by oxidation was reported. The reaction can be performed under mild conditions.
Synthesis of α-amino acids by addition of putative azido radicals to α-methoxy acrylonitriles derived from aldehydes and ketones
Clive, Derrick L. J.,Etkin, Nola
, p. 2459 - 2462 (2007/10/02)
α-Methoxy acrylonitriles, available from aldehydes and ketones, react with sodium azide in the presence of ceric ammonium nitrate to give azido nitrates; from these compounds, α-amino acids are obtained by sequential treatment with sodium acetate in acetic acid and then methanolic potassium carbonate, followed by hydrogenation.
