116876-36-9Relevant academic research and scientific papers
Effect of Silyl Substituent on Thermal Isomerization of Allene Episulfide. A New Aspect in Thioxyallyl Intermediate
Tokitoh, Norihiro,Choi, Nami,Ando, Wataru
, p. 2177 - 2180 (1987)
Kinetic studies on the thermal isomerization of 1,1-bis(trimethylsilyl)-3,3-diphenylallene 2-episulfide showed an attractive accelerating effect of silyl substituents attributable to the partial ionic nature of thioxyallyl intermediate.
SYNTHESIS AND REACTION OF NOVEL SULFUR CONTAINING HETEROCYCLIC SYSTEMS
Ando, Wataru,Tokitoh, Norihiro,Kabe, Yoshio
, p. 179 - 205 (2007/10/02)
The strained alkylidene episulfides were synthesized by carbene and alkylidene carbene additions to thiocarbonyl compounds.Thermal, photochemical, and acid catalyzed reactions have been extensively investigated, and the transition metal-promoted reaction
