116507-70-1Relevant academic research and scientific papers
Synthesis of nitrile oligomers through multiple anion capture reactions of allene dianions
Langer, Peter,Doering, Manfred,Seyferth, Dietmar,Goerls, Helmar
, p. 1948 - 1953 (2003)
Domino reactions between 1,1-dilithio-3,3-diphenylallene and nitriles resulted in the formation of products containing up to four nitrile molecules, representing the highest number to date of nitrile molecules involved in the formation of unambiguously ch
Direct transformation of silyl enol ethers into functionalized allenes
Langer, Peter,Doering, Manfred,Seyferth, Dietmar,Goerls, Helmar
, p. 573 - 584 (2007/10/03)
The first elimination reactions of silyl enol ethers to lithiated allenes are reported. These reactions allow a direct transformation of readily available silyl enol ethers into functionalized allenes. The action of three to four equivalents of lithium di
Synthesis and reactions of 2-alkylidene-1,3,4,-thiadiazolines and their selenium analogues
Choi, Nami,Tokitoh, Norihiro,Goto, Midori,Ando, Wataru
, p. 1189 - 1202 (2007/10/02)
2-Alkylidene-1,3,4-thiadiazoline 11a gave thioketone 16 (X=S) and acetylene derivative 17 on thermolysis via thiocarbonyl ylide, quantitatively. Pyrolysis of selenium analogue gave similar results. Allyl substituted 2-alkylidene-1,3,4-thiadiazolines 11a a
Effect of Silyl Substituent on Thermal Isomerization of Allene Episulfide. A New Aspect in Thioxyallyl Intermediate
Tokitoh, Norihiro,Choi, Nami,Ando, Wataru
, p. 2177 - 2180 (2007/10/02)
Kinetic studies on the thermal isomerization of 1,1-bis(trimethylsilyl)-3,3-diphenylallene 2-episulfide showed an attractive accelerating effect of silyl substituents attributable to the partial ionic nature of thioxyallyl intermediate.
