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CAS

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116889-37-3

C--N-(triphenylsilyl)nitrilimine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 116889-37-3 Structure

  • Basic information

    1. Product Name: C--N-(triphenylsilyl)nitrilimine
    2. Synonyms: C--N-(triphenylsilyl)nitrilimine
    3. CAS NO:116889-37-3
    4. Molecular Formula:
    5. Molecular Weight: 562.834
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 116889-37-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: C--N-(triphenylsilyl)nitrilimine(CAS DataBase Reference)
    10. NIST Chemistry Reference: C--N-(triphenylsilyl)nitrilimine(116889-37-3)
    11. EPA Substance Registry System: C--N-(triphenylsilyl)nitrilimine(116889-37-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 116889-37-3(Hazardous Substances Data)

116889-37-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 116889-37-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,6,8,8 and 9 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 116889-37:
(8*1)+(7*1)+(6*6)+(5*8)+(4*8)+(3*9)+(2*3)+(1*7)=163
163 % 10 = 3
So 116889-37-3 is a valid CAS Registry Number.

116889-37-3Relevant articles and documents

Synthesis and Reactivity of Stable Silyl-Substituted Nitrilimines

Castan, Florence,Baceiredo, Antoine,Bigg, Dennis,Bertrand, G.

, p. 1801 - 1807 (2007/10/02)

The reaction of chlorophosphanes and chlorosilanes with the lithium salts of the (bis(diisopropylamino)thiophosphoranyl)-, bis(diisopropylamino)phosphanyl)-, (trimethylsilyl)-, and (triisopropylsilyl)diazomethane (1, 4, 5, 6) has been studied.Four isolable nitrilimines XYNNY (X=(iPr2N)2P(S), Y=SiiPr3, 10a; X=(iPr2N)2P, Y=SiPh3, 14a; X=(iPr2N)2P, Y=SiiPr3, 15a; X=Y=SiiPr3, 18a) and three observable nitrilimines (X=(iPr2N)2P(S), Y=SiMe3, 8a; X=(iPr2N)2P(S), Y=SiPh3, 9a; X=(iPr2N)2P, Y=SiMe3, 13a) have been obtained.The factors influencing the stability of nitrilimines are analyzed.Several examples of thermal nitrilimine-diazo rearrangements and photochemical nitrilimine-carbodiimide rearrangements are described.The regioselectivity of the reaction of the observable nitrilimines with methyl acrylate and methyl propiolate is compared to that reported for transient nitrilimines.An example of 1,3-addition of butyllithium to nitrilimine is given.

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