1169881-04-2

Basic information

• Product Name: fac-[Re(I)Br(CO)3(3-phenyl-2H-azirine)2]
• CAS NO: 1169881-04-2
• Molecular Weight: 584.443
• Mol File: 1169881-04-2.mol

Chemical Properties

• CAS DataBase Reference: fac-[Re(I)Br(CO)3(3-phenyl-2H-azirine)2](CAS DataBase Reference)
• NIST Chemistry Reference: fac-[Re(I)Br(CO)3(3-phenyl-2H-azirine)2](1169881-04-2)
• EPA Substance Registry System: fac-[Re(I)Br(CO)3(3-phenyl-2H-azirine)2](1169881-04-2)

Safety Data

• Hazardous Substances Data: 1169881-04-2(Hazardous Substances Data)

Upstream product

• 56488-71-2 [ReBr(CO)3(thf)]2 
• 7654-06-0 3-phenyl-2H-azirine 

Relevant articles and documents

2H-Azirines as ligands: Synthesis and structural characterization of (2H-3-arene-azirine)ReI(CO)3Br complexes

The synthesis and structural characterization of four 2H-azirine rhenium(I) complexes are described. Stabilization of the highly reactive and strained 3-arene-2H-azirine ligand through N-coordination to the transition metal is observed. The reaction of [Re(CO)3(THF)2Br] with 3-arene-2H-azirine ligands (az) in THF at -20 °C in a 1:2 molar ratio afforded the neutral bis-azirine complexes [Re(CO)3(az)2Br] (az = NCH2CC6H4R; R = -H, -Me, -Cl, -Br). After purification, all complexes have been fully characterized. The molecular structures of the novel rhenium(I) complexes exhibit slightly distorted octahedral coordination geometries around the metal centers with cis-bonded az ligands.