56488-71-2

Upstream product

• 109-99-9 tetrahydrofuran 
• 148051-40-5 Re2(μ-Br)2(CO)6(S8) 

Downstream Products

• 1190886-32-8 fac-[(2-(3-ferrocenylprop-2-ylidene)-4,5-bis(diphenylphosphino)4-cyclopenten-1,3-dione)monobromotricarbonylrhenium(I)] 
• 1190848-85-1 fac-[(2-(ferrocenylidene)-4,5-bis(diphenylphosphino)4-cyclopenten-1,3-dione)monobromotricarbonylrhenium(I)] 
• 1169881-07-5 fac-[Re(I)Br(CO)3(3-p-bromophenyl-2H-azirine)2] 
• 1169881-06-4 fac-[Re(I)Br(CO)3(3-p-chorophenyl-2H-azirine)2] 
• 1169881-04-2 fac-[Re(I)Br(CO)3(3-phenyl-2H-azirine)2] 
• 1169881-05-3 fac-[Re(I)Br(CO)3(3-p-tolyl-2H-azirine)2] 
• 952190-34-0 fac-BrRe(CO)3(2-(2-thienylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione) 
• 880266-41-1 [Re(CO)3Br(4-(5-(4-diphenylaminophenylethynyl)pyridine)benzonitrile)]2 
• 880266-42-2 [Re(CO)3Br(4-(5-(naphthalen-1-yl-phenylamino)pyridin-2-ylethynyl)benzonitrile)]2 
• 880266-44-4 [Re(CO)3Br(4-(6-(naphthalen-1-yl-phenylamino)pyridin-3-ylethynyl)benzonitrile)2] 
• 880266-43-3 [Re(CO)3Br(4-(5-diphenylaminopyrimidin-2-ylethynyl)benzonitrile)]2 
• 143187-61-5 Re(Br)(CO)3(((C₆H₅)2P)2C₄O₃) 

Relevant academic research and scientific papers

Coordination of cyclo-octasulfur and cyclo-heptaselenium to dinuclear rhenium(I) systems

By substitution reactions of the coordinated THF ligands of Re2(μ-X)2(CO)6(THF)2 by elemental chalcogens (S8 and red selenium), the complexes Re2(μ-X)2(CO)6(S8) (X = Br, 1; 1, 2), and Re2(μ-X)2(CO)6(Se7), (X = I, 3; Br, 4) have been prepared. Binuclear compound 3 was crystallographically established to be a coordination compound of cyclo-heptaselenium, two adjacent selenium atoms of the Se7 ligand [Se-Se distance, 2.558(3) A] being bonded to rhenium(I), at an average Re-Se distance of 2.586(3) A, and the nonbonding ReRe distance being 4.077(3) A. Spectroscopic evidence of the existence of these chalcogen complexes in solution is reported. The Re2(μ-X)2(CO)6(S8) complexes undergo S8 displacement by THF, while the coordinated Se7 moiety is less readily displaced from 3.