117106-68-0Relevant academic research and scientific papers
REARRANGEMENT APPROACHES TO CYCLIC SKELETONS. V. FORMAL BRIDGEHEAD SUBSTITUTION OF 1-METHOXYBICYCLONON-6-EN-2-ONES AND ITS APPLICATION TO A TOTAL SYNTHESIS OF (+/-)-WIDDROL
Uyehara, Tadao,Yamada, Jun-Ichi,Furuta, Toshiaki,Kato, Tadahiro,Yamamoto, Yoshinori
, p. 5605 - 5620 (2007/10/02)
The C-1 methoxy group of bicyclonon-6-en-2-ones is replaced by alkyl, alkenyl, and aryl groups or hydrogen with inversion of the absolute configuration via the two-step sequence consists of Grignard reaction or reduction of the carbonyl followed by
