94786-85-3

Upstream product

• 100692-91-9 1-methoxy-5-methylbicyclo<3.2.2>non-6-en-2-one 
• 100692-91-9 1-Methoxy-5-methyl-bicyclo[3.2.2]non-6-en-2-one 
• 108-86-1 bromobenzene 

Downstream Products

• 117106-68-0 5-methyl-1-phenylbicyclo<3.2.2>nonan-2-one 
• 101968-44-9 5-methyl-1-phenylbicylo<3.2.2>non-3-en-2-one 
• 94768-53-3 (1R,3aS,7aR)-6-Methoxy-3a-methyl-1-phenyl-2,3,3a,4,5,7a-hexahydro-1H-inden-1-ol 
• 101968-37-0 5-methyl-1-phenylbicyclo<3.2.2>non-6-en-2-one 
• 101968-44-9 5-Methyl-1-phenyl-bicyclo[3.2.2]non-3-en-2-one 
• 101968-37-0 (1R,5R)-5-Methyl-1-phenyl-bicyclo[3.2.2]non-6-en-2-one 

Relevant academic research and scientific papers

REARRANGEMENT APPROACHES TO CYCLIC SKELETONS. V. FORMAL BRIDGEHEAD SUBSTITUTION OF 1-METHOXYBICYCLONON-6-EN-2-ONES AND ITS APPLICATION TO A TOTAL SYNTHESIS OF (+/-)-WIDDROL

The C-1 methoxy group of bicyclonon-6-en-2-ones is replaced by alkyl, alkenyl, and aryl groups or hydrogen with inversion of the absolute configuration via the two-step sequence consists of Grignard reaction or reduction of the carbonyl followed by

ALKOXIDE-ACCELERATED SIGMATROPIC SHIFTS OF BICYCLONON-6-EN-2-OLS. SUBSTITUENT EFFECTS AND TANDEM - SIGMATROPIC REARRANGEMENTS

Bicyclonon-6-en-2-ols are shown to undergo sigmatropic shifts under the influence of KH and 18-crown-6.A series of the 2-endo-vinyl alcohols were transformed into the ring-expanded ketones, bicycloundec-8-en-4-ones, via the tandem - sigmatropic rearrangements.