117212-80-3

Upstream product

• 117212-79-0 methyl 2,3-dimethylcyclohex-1-enecarboxylate 

Downstream Products

• 117305-95-0 2-[2-((1R,2S,6R)-2-Methoxymethoxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117305-95-0 2-[2-((1R,2R,6R)-2-Methoxymethoxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117305-95-0 2-[2-((1R,6S)-2-Methoxymethoxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-38-8 2-[2-((1S,6R)-1,6-Dimethyl-2-oxo-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-38-8 2-[2-((1S,6S)-1,6-Dimethyl-2-oxo-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-42-4 2-[2-((1S,2R,6S)-2-Hydroxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-42-4 2-[2-((1S,2S,6S)-2-Hydroxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-42-4 2-[2-((1S,6R)-2-Hydroxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-62-8 2-{2-[(1R,6S)-2-(tert-Butyl-dimethyl-silanyloxy)-1,6-dimethyl-cyclohex-3-enyl]-ethyl}-2-phenylselanyl-malonic acid dimethyl ester 
• 117211-37-7 2-[2-(1,6-Dimethyl-2-oxo-3-phenylselanyl-cyclohexyl)-ethyl]-malonic acid dimethyl ester 
• 117211-61-7 2-{2-[(1R,6S)-2-(tert-Butyl-dimethyl-silanyloxy)-1,6-dimethyl-cyclohex-3-enyl]-ethyl}-malonic acid dimethyl ester 
• 117211-57-1 2-Iodo-2-[2-((1R,6S)-2-methoxymethoxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-43-5 2-[2-(1,2-Dimethyl-6-methylene-cyclohexyl)-ethylidene]-malonic acid dimethyl ester 
• 117211-36-6 2-[2-(1,2-Dimethyl-6-oxo-cyclohexyl)-ethyl]-malonic acid dimethyl ester 

Relevant academic research and scientific papers

SYNTHESIS OF (+/-)-14-EPIUPIAL BY MANGANESE(III) γ-LACTONE ANNULATION

The total synthesis of racemic 14-epiupial (3) is described.The preparation of 3 is achieved in 23 steps starting from 8.In the key step, manganese(III) acetate acts on the monocarboxylic acid derived from 17b to promote concurrent formation of the bicycl