117211-57-1Relevant articles and documents
SYNTHESIS OF (+/-)-14-EPIUPIAL BY MANGANESE(III) γ-LACTONE ANNULATION
Paquette, Leo A.,Schaefer, Anthony G.,Springer, James P.
, p. 5567 - 5582 (2007/10/02)
The total synthesis of racemic 14-epiupial (3) is described.The preparation of 3 is achieved in 23 steps starting from 8.In the key step, manganese(III) acetate acts on the monocarboxylic acid derived from 17b to promote concurrent formation of the bicycl