117228-01-0

Basic information

• Product Name: (η-Cp)Fe(CO){P(OCy)3}COMe
• CAS NO: 117228-01-0
• Molecular Weight: 520.429
• Mol File: 117228-01-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η-Cp)Fe(CO){P(OCy)3}COMe(CAS DataBase Reference)
• NIST Chemistry Reference: (η-Cp)Fe(CO){P(OCy)3}COMe(117228-01-0)
• EPA Substance Registry System: (η-Cp)Fe(CO){P(OCy)3}COMe(117228-01-0)

Safety Data

• Hazardous Substances Data: 117228-01-0(Hazardous Substances Data)

Upstream product

• 15205-58-0 tricyclohexyl phosphite 

Relevant articles and documents

Separation of phosphorus(III) ligands into pure σ-donors and σ-donor/π-acceptors: Comparison of basicity and σ-donicity

The separation of phosphorus(III) ligands into two distinct groups identified as pure σ-donor ligands and σ-donor/π-acceptor ligands for the acetyl and methyl complexes, (η-Cp)FeL(CO)COMe, (η-Cp′)FeL-(CO)COMe (Cp′ = MeC5H4), and (η-Cp)FeL(CO)Me, is accomplished by correlation of the terminal carbonyl stretching frequencies with the EL°′ values. The basicity (pKa value of HPR3+) is related primarily to the σ-donicity (the ability of a ligand to donate σ-electrons to a transition metal) and to a lesser degree to the size of the ligand. We conclude that pKa values are reasonable measures of the σ-donicity for those ligands that are pure σ-donor ligands; a better measure are the χ values for those ligands that are pure σ-donors for both the iron complex and LNi(CO)3.