117236-96-1Relevant articles and documents
Tetraphenylborate Anion Oxidation by Acidic Co2+ Cations: Synthesis and Properties of Pyridine-Cobalt(I) Complexes
Fachinetti, Giuseppe,Funaioli, Tiziana,Zanazzi, Pier Francesco
, p. 1100 - 1101 (1988)
The neutral cobalt(I) complex Co(py)2(η-BPh4) (py=pyridine) was obtained on removal of py and thf (thf=tetrahydrofuran) from 2 and its crystal structure has been determined; in py as solvent, the former is converted into the ionic Co
Photochemical generation of pyridine- and polypyridine-Co(I) complexes by visible light irradiation of (BPh4)2 and (BPh4)2
Biagini, Paolo,Funaioli, Tiziana,Juris, Alberto,Fachinetti, Giuseppe
, p. C61 - C63 (1990)
The Co(bpy)32+ and Co(py)62+ complex cations form ion pairs with BPh4- counter-anions in pyridine solution.Excitation of the charge-transfer absorption band of the ion pair produces the corresponding Co(I) complexes, BPh4