Photochemical generation of pyridine- and polypyridine-Co(I) complexes by visible light irradiation of (BPh4)2 and (BPh4)2

DOI: 10.1016/0022-328X(90)85047-3

Source and publish data:

Journal of Organometallic Chemistry p. C61 - C63 (1990)

Update date:2022-08-11

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Authors:

Biagini, Paolo

Funaioli, Tiziana

Juris, Alberto

Fachinetti, Giuseppe

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Article abstract of DOI:10.1016/0022-328X(90)85047-3

The Co(bpy)3²⁺ and Co(py)6²⁺ complex cations form ion pairs with BPh4^- counter-anions in pyridine solution.Excitation of the charge-transfer absorption band of the ion pair produces the corresponding Co(I) complexes, BPh4<

Full text of DOI:10.1016/0022-328X(90)85047-3

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