1172607-87-2Relevant academic research and scientific papers
Palladium-Catalyzed Oxidative Borylation of Allylic C-H Bonds in Alkenes
Mao, Lujia,Bertermann, Rüdiger,Rachor, Simon G.,Szabó, Kálmán J.,Marder, Todd B.
, p. 6590 - 6593 (2017)
This communication describes an efficient palladium pincer complex-catalyzed allylic C-H borylation of alkenes. The transformation exhibits high regio- and stereoselectivity with a variety of linear alkenes. A synthetically useful feature of this allylic C-H borylation method is that all allyl-Bpin products can be isolated in usually high yields. Preliminary mechanistic studies indicate that this C-H borylation reaction proceeds via Pd(IV) pincer complex intermediates.
