117269-80-4

Basic information

• Product Name: (S)-4-[2-(2-tert-Butoxycarbonylamino-phenyl)-2-oxo-ethyl]-5-oxo-oxazolidine-3-carboxylic acid benzyl ester
• Synonyms: (S)-4-[2-(2-tert-Butoxycarbonylamino-phenyl)-2-oxo-ethyl]-5-oxo-oxazolidine-3-carboxylic acid benzyl ester
• CAS NO: 117269-80-4
• Molecular Weight: 454.48
• Mol File: 117269-80-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-4-[2-(2-tert-Butoxycarbonylamino-phenyl)-2-oxo-ethyl]-5-oxo-oxazolidine-3-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-[2-(2-tert-Butoxycarbonylamino-phenyl)-2-oxo-ethyl]-5-oxo-oxazolidine-3-carboxylic acid benzyl ester(117269-80-4)
• EPA Substance Registry System: (S)-4-[2-(2-tert-Butoxycarbonylamino-phenyl)-2-oxo-ethyl]-5-oxo-oxazolidine-3-carboxylic acid benzyl ester(117269-80-4)

Safety Data

• Hazardous Substances Data: 117269-80-4(Hazardous Substances Data)

Upstream product

• 3422-01-3 tert-butyl phenylcarbamate 
• 177723-78-3 (S)-3-(benzyloxycarbonyl)-5-oxo-4-oxazolidineacetyl chloride 
• 53623-87-3 (S)-3-(benzyloxycarbonyl)-5-oxo-4-oxazolidineacetic acid 
• 111197-44-5 (4S)-4-(Chloroformyl)methyl-3-[(phenylmethoxy)carbonyl]oxazolidin-5-one 
• 114552-32-8 N-tert-butoxycarbonyl-2-trimethylstannylaniline 
• 23632-66-8 (4S)-3-benzyloxycarbonyl-4-carboxymethyl-1,3-oxazolidin-5-one 
• 1152-61-0 N-Cbz-L-Asp 

Downstream Products

• 1331871-16-9 (S)-methyl 1-((S)-2-(((benzyloxy)carbonyl)amino)-4-(2-((tert-butoxycarbonyl)amino)phenyl)-4-oxobutanoyl)pyrrolidine-2-carboxylate 
• 1331871-18-1 C₂₀H₂₅N₃O₅ 
• 1331871-20-5 N-(2-(2-((3S,8aS)-1,4-dioxooctahydropyrrolo[1,2-a]pyrazin-3-yl)acetyl)phenyl)-4-methylpent-3-enamide 
• 117269-81-5 L-Kynurenine dihydrobromide 

Relevant articles and documents

Total synthesis of tryprostatins A and B

Three distinct synthetic routes to the 2-prenyl tryptophan core skeleton of tryprostatins and their total syntheses are described. The strategies include a traditional gramine-mediated coupling reaction, Fuerstner indole synthesis, and our radical-mediated indole synthesis from o-alkenylphenyl isocyanide. The establishment of reliable conditions for the radical-mediated construction of indoles via a low-temperature radical initiator V-70 (2,2′-azobis(4- methoxy-2,4-dimethylvaleronitrile)) led to the highly efficient syntheses of tryprostatins A and B.