117308-60-8

Basic information

• Product Name: C₁₀H₁₄S(Ge(C₆H₂(CH₃)3)2)2
• CAS NO: 117308-60-8
• Molecular Weight: 788.213
• Mol File: 117308-60-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₀H₁₄S(Ge(C₆H₂(CH₃)3)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₀H₁₄S(Ge(C₆H₂(CH₃)3)2)2(117308-60-8)
• EPA Substance Registry System: C₁₀H₁₄S(Ge(C₆H₂(CH₃)3)2)2(117308-60-8)

Safety Data

• Hazardous Substances Data: 117308-60-8(Hazardous Substances Data)

Upstream product

• 122967-96-8 C₁₀H₁₄SGe(C₆H₂(CH₃)3)2 
• 107824-85-1 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 115385-07-4 tetrakis(2,4,6-trimethylphenyl)digermene 
• 23695-65-0 adamantane-2-thione 
• 107824-84-0 hexamesitylcyclotrigermane 

Relevant articles and documents

Synthesis and chemistry of thiagermiranes

Dimethylgermylene (1) reacts with thioketones 3 and 9 to give 1,3,2,4-dithiadigermolanes 4 and 10, the ultimate products of formation of thiagermiranes 6 and 11 and subsequent addition of dimethylgermanethione (7). Dimesitylgermylene (16) reacts with adamantanethione (3) to give 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (18). Photolysis of thiagermirane 18 yields dimesitylgermylene (16) and adamantanethione (3) derived from germathiocarbonyl ylide 22. Oxidation of thiagermirane 18 by mCPBA gives 3-(2-adamantyl)-4,4-dimesityl-1,2,4-oxathiagermetane S-oxide (27). X-ray analyses were done for thiagermirane 18 and 1,2,4-oxathiagermetane S-oxide 27.