1173294-15-9Relevant academic research and scientific papers
Manganese(v)-oxo corroles in hydride-transfer reactions
Han, Yejee,Lee, Yong-Min,Mariappan, Mariappan,Fukuzumi, Shunichi,Nam, Wonwoo
, p. 8160 - 8162 (2010/12/19)
Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(v)-oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (E red) of manganese(v)-oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.
Nucleophilic attack of hydroxide on a Mnv oxo complex: A model of the O-O bond formation in the oxygen evolving complex of photosystem II
Gao, Yan,Akermark, Torbjoern,Liu, Jianhui,Sun, Licheng,Akermark, Bjoern
, p. 8726 - 8727 (2009/12/04)
(Figure Presented) A manganese(III) corrole complex, 1, has been synthesized and used to study a potential mechanism for oxidation of water to molecular oxygen. Oxidation by t-BuOOH gave the MnV=O complex 2. Addition of hydroxide led to release
