1173364-79-8

Upstream product

• 1417790-49-8 [(2,4-di-tert-butyl-6-(diisopropylaminomethyl)phenyl)GeC(N₂)SiMe₃] 
• 7732-18-5 water 
• 234074-90-9 1-bromo-2,4-di-tert-butyl-6-(diisopropylaminomethyl)benzene 
• 1173364-73-2 1-chloro-1-[4,6-di-tert-butyl-2-(diisopropylaminomethyl)phenyl]germylene 

Relevant academic research and scientific papers

Reactivity of a germa-alkyne: Evidence for a germanone intermediate in the hydrolysis and alcoholysis processes

The formation of a new transient germa-alkyne Ar-Ge{partial triple bond, top dashed}C-SiMe3 [Ar = 2,4-di-tert-butyl-6-(diisopropylaminomethyl)phenyl] is achieved by photolysis of the corresponding trimethylsilyldiazomethylgermylene ArGeC(N2)SiMe3 (2). The germa-alkyne is characterized by trapping reactions with H2O and an equimolar mixture of tert-butanol and water. The respective adducts, the gem-germanediol 5 and the alkoxygermanol 4 have been fully characterized by spectroscopic methods. A study of the mechanism is proposed and in both cases, the addition involves the transient formation of a germanone. The structures of 2 and 5 are determined by single-crystal X-ray diffraction.