234074-90-9

Upstream product

• 108-18-9 diisopropylamine 
• 154492-64-5 2-bromo-1-(bromomethyl)-3,5-di-tert-butylbenzene 

Downstream Products

• 1173364-77-6 [(2,4-di-tert-butyl-6-(diisopropylaminomethyl)phenyl)Ge(OH)(O-t-Bu)CH₂SiMe₃] 
• 1173364-79-8 [(2,4-di-tert-butyl-6-(diisopropylaminomethyl)phenyl)Ge(OH)2CH₂SiMe₃] 

Relevant academic research and scientific papers

Reactivity of a germa-alkyne: Evidence for a germanone intermediate in the hydrolysis and alcoholysis processes

The formation of a new transient germa-alkyne Ar-Ge{partial triple bond, top dashed}C-SiMe3 [Ar = 2,4-di-tert-butyl-6-(diisopropylaminomethyl)phenyl] is achieved by photolysis of the corresponding trimethylsilyldiazomethylgermylene ArGeC(N2)SiMe3 (2). The germa-alkyne is characterized by trapping reactions with H2O and an equimolar mixture of tert-butanol and water. The respective adducts, the gem-germanediol 5 and the alkoxygermanol 4 have been fully characterized by spectroscopic methods. A study of the mechanism is proposed and in both cases, the addition involves the transient formation of a germanone. The structures of 2 and 5 are determined by single-crystal X-ray diffraction.

Preparation and properties of stabilized thioxophosphine sulfides bearing the 4-t-butyl-2,6-bis(dialkylaminomethyl)phenyl or the 2,4-di-t- butyl-6-(dialkylaminomethyl)phenyl substituents

Stabilized thioxophosphine sulfides bearing the 4-t-butyl-2,6- bis(dialkylaminomethyl)phenyl or the 2,4-di-t-butyl- 6(dialkylaminomethyl)phenyl group, as well as their 15N labeled analogs, were prepared. Intramolecular interaction between the n