117371-67-2Relevant academic research and scientific papers
Regioselectivity of Reductive Cleavage of Methyl 4,6-O-Benzylidene-3-deoxyhexopyranosides Containing Fluorine at the 2- or 3-Position with LiAlH4-AlCl3
Mori, Yoko,Morishima, Naohiko
, p. 2061 - 2067 (2007/10/02)
Reductive ring-opening reactions of the 4,6-O-benzylidene derivatives of methyl 3-deoxy-β-D-arabino-, 3-deoxy-α-D-ribo-, and 2-O-benzyl-3-deoxy-α-D-ribo-hexopyranosides with LiAlH4 and AlCl3 in the molar ratio of 4:4 gave the 4- and 6-O-benzyl derivatives
Preferred Conformation of C-Glycosides. 8. Synthesis of 1,4-Linked Carbon Disaccharides
Wang, Yuan,Babirad, Stefan A.,Kishi, Yoshito
, p. 468 - 481 (2007/10/02)
Three general synthetic routes to 1,4-linked carbon disaccharides (e.g., 3, 4, 15-17, 21-23, 44, and 45) are presented.Control of the stereochemistry at C.1', C.2', C.5'and C.4, the incorporation of deuterium labels at the C.α position, and structural mod
Syntheses of specifically deoxygenated methyl α-isomaltotriosides
Petrakova,Kovac,Glaudemans
, p. 101 - 112 (2007/10/02)
Specifically deoxygenated methyl α-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected α-isomaltosyl chloride with suitably blocked derivatives of methyl α-D-glucopyranoside deoxygenated respectively at positi
Synthesis and biological activities of methyl oligobiosaminide and some deoxy isomers thereof.
Shibata,Kosuge,Ogawa
, p. 37 - 54 (2007/10/02)
Methyl oligobiosaminide (1) the core structure of oligostatin C, and five analogues, the 6-hydroxy-(2), 2-deoxy- (3), 2-deoxy-6-hydroxy- (4), 3-deoxy- (5), and 3-deoxy-6-hydroxy derivatives (6), were synthesized by coupling the protected pseudo-sugar epoxide 46 with suitable methyl 4-amino-4-deoxy-alpha-D-hexopyranoside derivatives. Compounds 3 and 6 showed notable inhibitory activity against alpha-D-glucosidase and alpha-D-mannosidase, respectively, whereas compound 1 had almost no activity.
