117371-67-2Relevant academic research and scientific papers
Regioselectivity of Reductive Cleavage of Methyl 4,6-O-Benzylidene-3-deoxyhexopyranosides Containing Fluorine at the 2- or 3-Position with LiAlH4-AlCl3
Mori, Yoko,Morishima, Naohiko
, p. 2061 - 2067 (2007/10/02)
Reductive ring-opening reactions of the 4,6-O-benzylidene derivatives of methyl 3-deoxy-β-D-arabino-, 3-deoxy-α-D-ribo-, and 2-O-benzyl-3-deoxy-α-D-ribo-hexopyranosides with LiAlH4 and AlCl3 in the molar ratio of 4:4 gave the 4- and 6-O-benzyl derivatives
Syntheses of specifically deoxygenated methyl α-isomaltotriosides
Petrakova,Kovac,Glaudemans
, p. 101 - 112 (2007/10/02)
Specifically deoxygenated methyl α-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected α-isomaltosyl chloride with suitably blocked derivatives of methyl α-D-glucopyranoside deoxygenated respectively at positi
Preferred Conformation of C-Glycosides. 8. Synthesis of 1,4-Linked Carbon Disaccharides
Wang, Yuan,Babirad, Stefan A.,Kishi, Yoshito
, p. 468 - 481 (2007/10/02)
Three general synthetic routes to 1,4-linked carbon disaccharides (e.g., 3, 4, 15-17, 21-23, 44, and 45) are presented.Control of the stereochemistry at C.1', C.2', C.5'and C.4, the incorporation of deuterium labels at the C.α position, and structural mod
Synthesis and biological activities of methyl oligobiosaminide and some deoxy isomers thereof.
Shibata,Kosuge,Ogawa
, p. 37 - 54 (2007/10/02)
Methyl oligobiosaminide (1) the core structure of oligostatin C, and five analogues, the 6-hydroxy-(2), 2-deoxy- (3), 2-deoxy-6-hydroxy- (4), 3-deoxy- (5), and 3-deoxy-6-hydroxy derivatives (6), were synthesized by coupling the protected pseudo-sugar epoxide 46 with suitable methyl 4-amino-4-deoxy-alpha-D-hexopyranoside derivatives. Compounds 3 and 6 showed notable inhibitory activity against alpha-D-glucosidase and alpha-D-mannosidase, respectively, whereas compound 1 had almost no activity.
