1174000-75-9Relevant academic research and scientific papers
Hydroacylation of 2-butyne from the alcohol or aldehyde oxidation level via ruthenium catalyzed C-C bond forming transfer hydrogenation
Williams, Vanessa M.,Leung, Joyce C.,Patman, Ryan L.,Krische, Michael J.
supporting information; experimental part, p. 5024 - 5029 (2009/10/24)
Under the conditions of ruthenium catalyzed transfer hydrogenation, 2-butyne couples to alcohols 1a-1j to deliver α,β-unsaturated ketones 3a-3j in good to excellent isolated yields with complete E-stereoselectivity. Under identical conditions, aldehydes 2
