98689-60-2

Upstream product

• 10229-10-4 pent-3-yn-1-ol 
• 100-39-0 benzyl bromide 
• 57618-47-0 5-benzyloxy-1-pentyne 

Downstream Products

• 98689-62-4 (E)-5-benzyloxy-2-trimethylsilyl-2-pentene 
• 98689-61-3 ((Z)-3,4-Bis-trimethylsilanyl-pent-3-enyloxymethyl)-benzene 
• 98689-63-5 (E)-5-benzyloxy-3-deuterio-2-trimethylsilyl-2-pentene 
• 10229-10-4 pent-3-yn-1-ol 
• 98689-64-6 (E)-5-benzyloxy-3-methyl-2-trimethylsilyl-2-pentene 
• 43142-58-1 3-ethylidenedihydro-2(3H)-furanone 
• 72649-02-6 5,6-dihydro-3-methyl-2H-pyran-2-one 
• 100-51-6 benzyl alcohol 
• 98689-66-8 (Z)-pent-3-en-1-yloxymethylbenzene 
• 119968-36-4 5-benzyloxy-2-(dimethylphenylsilyl)-2-pentene 
• 1174000-75-9 (E)-2-(2-benzyloxyethyl)-1-(4-bromophenyl)but-2-en-1-one 
• 1352848-45-3 (E)-3-(2-(benzyloxy)ethyl)dodec-2-en-4-ol 
• 1352849-90-1 (E)-2-(3-(2-(benzyloxy)-ethyl)-2-hydroxypent-3-enyl)-isoindoline-1,3-dione 
• 1352849-13-8 (E)-1-(benzyloxy)-3-(2-(benzyloxy)ethyl)pent-3-en-2-ol 

Relevant academic research and scientific papers

Ligand-Enabled, Copper-Catalyzed Regio- and Stereoselective Synthesis of Trialkylsubstituted Alkenylboronates from Unactivated Internal Alkynes

We report the first copper-catalyzed regio- and stereoselective borylalkylation of dialkylsubstituted internal alkynes with bis(pinacolato)diboron and alkyl halides. A catalytically generated borylcopper species containing a novel π-accepting N-heterocycl

Soft propargylic deprotonation: Designed ligand enables au-catalyzed isomerization of alkynes to 1,3-Dienes

By functionalizing the privileged biphenyl-2-ylphosphine with a basic amino group at the rarely explored 3′ position, the derived gold(I) complex possesses orthogonally positioned "push" and "pull" forces, which enable for the first time soft propargylic deprotonation and permit the bridging of a difference of >26 pKa units (in DMSO) between a propargylic hydrogen and a protonated tertiary aniline. The application of this design led to efficient isomerization of alkynes into versatile 1,3-dienes with synthetically useful scope under mild reaction conditions.

Preparation of iniidazolin-2-iminato molybdenum and tungsten benzylidyne complexes: A new pathway to highly active alkyne metathesis catalysts

The reaction of [PhC=MBr3(dme)] (dme = 1,2-dimethoxyethane) with the hexafluoro-fert-butoxides LiJ. or KX [X = OC(CF3)2Me] afforded the benzylidyne complexes [PhC=MX3(dme)] (2a: M = W, 2b: M = Mo), which further

Hexafluoroisopropanol as a unique solvent for stereoselective lododesilylation of vinylsilanes

Stereoselective preparation of iodoalkenes from vinylsilanes is described. 1,1,1,3,3,3-Hexafluoroisopropanol serves as a unique solvent that ensures high yields and stereoselectivities in the iododesilylation of a variety of functionalized substrates.

Highly selective hydrogenation of multiple carbon-carbon bonds promoted by nickel(0) nanoparticles

A new method for the highly stereoselective cis semihydrogenation of internal alkynes, semihydrogenation of terminal alkynes, reduction of dienes to alkenes, and reduction of alkynes and alkenes to alkanes is described based on in situ generated both Ni(0) nanoparticles and molecular hydrogen.