1174332-94-5Relevant articles and documents
Diverting β-Hydride Elimination of a ?-Allyl PdIICarbene Complex for the Assembly of Disubstituted Indolines via a Highly Diastereoselective (4 + 1)-Cycloaddition
Tucker, Zachary D.,Hill, Harrison M.,Smith, Andrew L.,Ashfeld, Brandon L.
, p. 6605 - 6609 (2020)
A Pd0-catalyzed formal (4 + 1)-cycloaddition approach to 2,3-disubstituted dihydroindoles is described. The diastereoselective formation of dihydroindoles that is highlighted by a carbene migratory insertion/reductive elimination sequence proceeding via a ?-allyl PdII-species compliments existing methods of indoline assembly.