1174402-06-2Relevant academic research and scientific papers
Cascade Multiple Diels-Alder Reactions of Styrene Derivatives with Maleimide or Maleic Anhydride
Yoshioka, Shohei,Aoyama, Hiroshi,Fujioka, Hiromichi,Arisawa, Mitsuhiro
, p. 6599 - 6606 (2018)
We developed novel one-pot multiple Diels-Alder reactions, which are frequently used in the construction of six-membered rings in functional molecular synthesis. We report triple and double Diels-Alder reactions with styrene derivatives, where the secondary Diels-Alder reaction takes place at a different position from that of the conventional Wagner-Jauregg reaction.
Ruthenium-catalyzed tandem enyne metathesis/hydrovinylation
Gavenonis, Jason,Arroyo, Ruben V.,Snapper, Marc L.
supporting information; experimental part, p. 5692 - 5694 (2010/09/10)
In situ modification of Grubbs' first-generation metathesis catalyst allows for a tandem enyne metathesis/hydrovinylation that is complementary to the regioselectivity of known ruthenium-catalyzed hydrovinylations.
Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes
Lee, Yeon-Ju,Schrock, Richard R.,Hoveyda, Amir H.
supporting information; experimental part, p. 10652 - 10661 (2009/12/04)
Stereogenic-at-Mo monoalkoxide and monoaryloxide complexes promote enyne ring-closing metathesis (RCM) reactions, affording the corresponding endo products with high selectivity (typically >98: 2 endo:exo). All catalysts can be prepared and used in situ.
