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2-((4-fluorophenyl)thio)-1-phenylethan-1-ol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1174708-84-9

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1174708-84-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1174708-84-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,7,4,7,0 and 8 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1174708-84:
(9*1)+(8*1)+(7*7)+(6*4)+(5*7)+(4*0)+(3*8)+(2*8)+(1*4)=169
169 % 10 = 9
So 1174708-84-9 is a valid CAS Registry Number.

1174708-84-9Downstream Products

1174708-84-9Relevant academic research and scientific papers

Visible-Light-Induced Hydroxysulfurization and Alkoxysulfurization of Styrenes in the Absence of Photocatalyst: Synthesis of β-Hydroxysulfides and β-Alkoxysulfides

Ruan, Hongjie,Meng, Ling-Guo,Zhu, Lingqiong,Wang, Lei

, p. 3217 - 3222 (2019)

We developed hydroxysulfurization and alkoxysulfurization of styrenes using a visible-light synthetic strategy in the absence of photocatalyst and oxidant. This strategy provided the corresponding β-hydroxysulfides and β-alkoxysulfides in moderate to good yields with high regioselectivity. The reaction was tolerated by a wide range of functional groups. This is the first example of ArSSAr/CBr4 system has been introduced into organic transformation. (Figure presented.).

Light-Promoted and Tertiary-Amine-Assisted Hydroxysulfenylation of Alkenes: Selective and Direct One-Pot Synthesis of β-Hydroxysulfides

Shi, Jing,Gao, Xue-Wang,Tong, Qing-Xiao,Zhong, Jian-Ji

, p. 12922 - 12931 (2021/09/18)

A light-promoted and tertiary-amine-assisted strategy for efficient hydroxysulfenylation of both electron-rich and electron-deficient alkenes with thiophenols to selectively and directly access β-hydroxysulfides in one pot is described herein. In contrast to the previously reported thiol-oxygen co-oxidation reactions, this simple and sustainable approach features mild reaction conditions, high efficiency, and excellent functional group tolerance.

Air oxidative radical hydroxysulfurization of styrenes leading to β-hydroxysulfides

Zhou, Shao-Fang,Pan, Xiangqiang,Zhou, Zhi-Hao,Shoberu, Adedamola,Zou, Jian-Ping

, p. 3682 - 3687 (2015/04/14)

Air oxidative radical hydroxysulfurization of styrenes initiated by 0.5 mol % of tert-butyl hydroperoxide with arylthiols is described, and a new type of difunctionalization of alkenes was achieved.

Aerobic oxysulfonylation of alkenes using thiophenols: An efficient one-pot route to β-ketosulfones

Singh, Atul K.,Chawla, Ruchi,Keshari, Twinkle,Yadav, Vinod K.,Yadav, Lal Dhar S.

supporting information, p. 8550 - 8554 (2014/12/10)

We have developed a highly efficient synthetic route to β-ketosulfones via AgNO3 catalyzed oxysulfonylation of alkenes using thiophenols in the presence of air (O2) and K2S2O8 as eco-friendly oxidants. Thiophenols have been used as sulfonylation precursors for the first time in a dioxygen activation based radical process. Moreover, the protocol also offers a new and convenient method for the synthesis of β-hydroxysulfides at room temperature without the use of any initiator. This journal is

Tandem base-free synthesis of β-hydroxy sulphides under ultrasound irradiation

Lv, Guang-Shu,Duan, Fu-Jun,Ding, Jin-Chang,Cheng, Tian-Xing,Gao, Wen-Xia,Chen, Jiu-Xi,Wu, Hua-Yue

, p. 1057 - 1062 (2013/03/13)

Rongalite promotes cleavage of diaryl disulphides generating the corresponding thiolate species in situ which then undergo facile ring-opening of epoxides in a regioselective manner under ultrasound irradiation, affording β-hydroxy sulphides in good to ex

Rongalite promoted highly regioselective synthesis of β-hydroxy sulfides by ring opening of epoxides with disulfides

Guo, Wenxue,Chen, Jiuxi,Wu, Dengze,Ding, Jinchang,Chen, Fan,Wu, Huayue

experimental part, p. 5240 - 5243 (2009/11/30)

Rongalite promotes cleavage of disulfides generating thiolate anions that then undergo facile ring opening of epoxides in the presence of K2CO3 to afford α-addition products 3 with good to excellent yields. The important f

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