117481-26-2

Upstream product

• 68494-08-6 4,5-bis(benzoylthio)-1,3-dithiole-2-thione 

Downstream Products

• 201612-45-5 ((C₆H₅)3P)2N⁽¹⁺⁾*Au(C₃S₄Se)2^(1-)=[((C₆H₅)3P)2N][Au(C₃S₄Se)2] 
• 201612-37-5 Au₂(C₃S₄Se)(((C₆H₅)2PCH₂)2) 
• 201612-32-0 Au₂(C₃S₄Se)(P(C₆H₅)2CH₃)2 
• 201612-30-8 Au₂(C₃S₄Se)(P(C₆H₅)3)2 
• 201612-31-9 Au₂(C₃S₄Se)(P(C₆H₄OCH₃)3)2 
• 201612-42-2 (C₄H₉)4N⁽¹⁺⁾*Au(C₃S₄Se)(P(C₆H₅)2CH₃)^(1-)=[(C₄H₉)4N][Au(C₃S₄Se)(P(C₆H₅)2CH₃)] 
• 201612-40-0 (C₄H₉)4N⁽¹⁺⁾*Au(C₃S₄Se)(P(C₆H₅)3)^(1-)=[(C₄H₉)4N][Au(C₃S₄Se)(P(C₆H₅)3)] 
• 88203-73-0 Tetrakis(benzoylthio)-tetrathiofulvalen 

Relevant academic research and scientific papers

The New Synthetic Metals of M(dmise)2: 2 and (EDT-TTF)

Both of the newly synthesized 2 and (EDT-TTF) exhibit metallic behaviour around room temperature at ambient pressure; tight-binding band calculation indicates that the former has a nearly three-dimensional Fermi surface owi

2-(Triphenylphosphonio)-4,5-bis(benzoylthio)-1,3-dithiole Tetrafluoroborate: A Versatile Wittig Reagent for the Synthesis of Unsymmetrical Tetrathiafulvalenes and 1,3-Dithiol-2-ylidene Derivatives

The title Wittig reagent 5 has been prepared in three steps (84percent overall yield) from 4,5-bis(benzoylthio)-1,3-dithiole-2-thione.Reactions of ylide 7, generated by treatment of 5 with diisopropylethylamine at room temperature, have been exploited in the synthesis of new unsymmetrical tetrathiafulvalenes and 1,3-dithiol-2-ylidene derivatives.Subsequent removal of the benzoyl protecting group with sodium ethoxide liberates the transient TTF-dithiolate or 1,3-dithiole-dithiolate anions which can be alkylated in situ.The X-ray crystal structures of compounds 17 and 18 are reported: close nonbonded S...O intramolecular interactions are observed in both structures.