1174895-55-6Relevant articles and documents
Pyridine-directed carbon–carbon single bond activation: Rhodium-catalyzed decarbonylation of aryl and heteroaromatic ketones
Johnson, Jeffrey B.,Salisbury, Eric A.,Schoonover, Erik J.,VanderRoest, Jacob P.,Wagner, Cole J.
, (2021/07/28)
The decarbonylation of 2-pyridyl-substituted ketones via transition metal-catalyzed carbon–carbon bond activation provides ready access to a variety of biaryl compounds. The highly efficient and general method provides reliable decarbonylation of benzophenones including a range of functional groups and substitution patterns. The methodology has also proven highly efficient for heteroaromatic substrates, including those containing thiophenyl, indolyl, quinolinyl, and pyridine substitution.
Combination of RuCl3·: X H2O with PEG-a simple and recyclable catalytic system for direct arylation of heteroarenes via C-H bond activation
Jian, Lei,He, Hai-Yu,Huang, Jin,Wu, Qian-Hui,Yuan, Mao-Lin,Fu, Hai-Yan,Zheng, Xue-Li,Chen, Hua,Li, Rui-Xiang
, p. 23515 - 23522 (2017/07/07)
A simple and recyclable catalytic system for direct arylation of heteroarenes via C-H bond activation was developed with a relatively inexpensive RuCl3·xH2O as a catalyst and PEG-400 as a green medium without any additive or ligand.
Ruthenium complexes of κ(P)-and κ(P)-η6- coordinated KITPHOS monophosphines: Efficient catalysts for the direct ortho arylation of 2-phenylpyridine and N-phenylpyrazole with aryl chlorides
Doherty, Simon,Knight, Julian G.,Addyman, Carrie R.,Smyth, Catherine H.,Ward, Nicholas A. B.,Harrington, Ross W.
experimental part, p. 6010 - 6016 (2012/01/14)
Thermolysis of the P-coordinated KITPHOS monophosphine complex [(p-cymene)RuCl2(KITPHOS)] in chlorobenzene at 120 °C resulted in displacement of the p-cymene to afford [{κ(P)-η 6-KITPHOS} RuCl2], the first example of a con
