117593-99-4Relevant academic research and scientific papers
APPLICATIONS OF THE FLUORINATED 1,3-DIPOLAR COMPOUNDS AS THE BUILDING BLOCKS OF THE HETEROCYCLES WITH FLUORINE GROUPS. PART XII. SYNTHESIS OF TRIFLUOROMETHYLISOXAZOLINES AND THEIR REARRANGEMENT INTO TRIFLUOROMETHYLAZIRIDINES
Tanaka, K.,Ohsuga, M.,Sugimoto, Y.,Okafuji, Y.,Mitsuhashi, K.
, p. 39 - 46 (1988)
N-Methyl-C-trifluoromethylnitrone cycloadded with various alkynes to give 3-trifluoromethyl-4-isoxazolines.The isolated isoxazolines further underwent the valence rearrangement into 2-trifluoromethylaziridines under more drastic conditions.Unusual stabili
