APPLICATIONS OF THE FLUORINATED 1,3-DIPOLAR COMPOUNDS AS THE BUILDING BLOCKS OF THE HETEROCYCLES WITH FLUORINE GROUPS. PART XII. SYNTHESIS OF TRIFLUOROMETHYLISOXAZOLINES AND THEIR REARRANGEMENT INTO TRIFLUOROMETHYLAZIRIDINES

DOI: 10.1016/S0022-1139(00)82735-9

Source and publish data:

Journal of Fluorine Chemistry p. 39 - 46 (1988)

Update date:2022-08-05

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Authors:

Tanaka, K.

Ohsuga, M.

Sugimoto, Y.

Okafuji, Y.

Mitsuhashi, K.

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Article abstract of DOI:10.1016/S0022-1139(00)82735-9

N-Methyl-C-trifluoromethylnitrone cycloadded with various alkynes to give 3-trifluoromethyl-4-isoxazolines.The isolated isoxazolines further underwent the valence rearrangement into 2-trifluoromethylaziridines under more drastic conditions.Unusual stabili

Full text of DOI:10.1016/S0022-1139(00)82735-9

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