117606-40-3

Upstream product

• 27891-73-2 β-phenylsulfanyl lactoside 
• 117606-38-9 (4aR,6S,7R,8R,8aR)-6-((2R,3S,4R,5R,6S)-4,5-Dihydroxy-2-hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 3282-30-2 pivaloyl chloride 
• 117606-39-0 phenyl O-(4,6-di-O-isopropylidene-2,3-di-O-pivaloyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-pivaloyl-1-thio-β-D-glucopyranoside 

Downstream Products

• 117606-41-4 phenyl O-(6-O-benzoyl-2,3-di-O-pivaloyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-pivaloyl-1-thio-β-D-glucopyranoside 

Relevant academic research and scientific papers

Total synthesis of globotriaosylceramide (Gb3) and lysoglobotriaosylceramide (lysoGb3)

We have recently reported a highly efficient and stereocontrolled synthesis of globotriaosylceramide (Gb3, 1) in optically pure form.Key to our synthetic strategy was the implementation of the two-stage activation of thioglycosides for formatio