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117607-12-2

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117607-12-2 Usage

General Description

(S)-benzyl 2-methylpyrrolidine-1-carboxylate is a chemical compound with the molecular formula C14H17NO2. It is a derivative of pyrrolidine and is used in the synthesis of pharmaceuticals and other organic compounds. (S)-benzyl 2-methylpyrrolidine-1-carboxylate has a chiral center, meaning it has two mirror-image forms (enantiomers) that have different chemical and biological properties. It is commonly used as a building block in the production of various drugs and active pharmaceutical ingredients. Additionally, it has been studied for its potential biological activities and is of interest to researchers in the field of medicinal chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 117607-12-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,7,6,0 and 7 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 117607-12:
(8*1)+(7*1)+(6*7)+(5*6)+(4*0)+(3*7)+(2*1)+(1*2)=112
112 % 10 = 2
So 117607-12-2 is a valid CAS Registry Number.

117607-12-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name (R)-2-methyl-1-pyrrolidinecarboxylic acid phenylmethyl ester

1.2 Other means of identification

Product number -
Other names (S)-2-Methyl-1-pyrrolidinecarboxylic acid benzyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:117607-12-2 SDS

117607-12-2Relevant articles and documents

Asymmetric intramolecular hydroamination of alkenes in mild and wet conditions - Structure and reactivity of cationic binuclear gold(I) catalysts

Abadie, Marc-Antoine,Trivelli, Xavier,Medina, Florian,Capet, Frederic,Roussel, Pascal,Agbossou-Niedercorn, Francine,Michon, Christophe

, p. 2235 - 2239 (2014)

A selected diphosphine binuclear gold(I) chloride complex was combined with a silver salt to catalyze efficiently, for the first time, the asymmetric intramolecular hydroamination of alkenes with high conversions and enantioselectivities, in mild conditions and in presence of water. Both enantiomers of the products could be obtained by controlling the molecular ion-pairs through the solvent polarity. The gold(I) cationic active species was characterized unambiguously at the solid state by X-ray analysis and in solution by DOSY 1H NMR experiments. No contribution of silver chloride was observed on the bonding mode of the catalyst.

Catalytic Reduction of Alkyl and Aryl Bromides Using Propan-2-ol

Haibach, Michael C.,Stoltz, Brian M.,Grubbs, Robert H.

supporting information, p. 15123 - 15126 (2017/11/20)

Milstein's complex, (PNN)RuHCl(CO), catalyzes the efficient reduction of aryl and alkyl halides under relatively mild conditions by using propan-2-ol and a base. Sterically hindered tertiary and neopentyl substrates are reduced efficiently, as well as more functionalized aryl and alkyl bromides. The reduction process is proposed to occur by radical abstraction/hydrodehalogenation steps at ruthenium. Our research represents a safer and more sustainable alternative to typical silane, lithium aluminium hydride, and tin-based conditions for these reductions.

Stereochemical aspects of the 'tert-amino effect'. 2. Enantio- and diastereoselectivity in the synthesis of quinolines, pyrrolo[1,2-a]quinolines, and [1,4]oxazino[4,3-a]quinolines

Nijhuis,Verboom,Abu El-Fadl,Van Hummel,Reinhoudt

, p. 209 - 216 (2007/10/02)

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