117607-52-0Relevant academic research and scientific papers
Rapid Intramolecular Addition Reactions of Triplet Arylcarbenes
Hoemberger, Guenter,Dorigo, Andrea E.,Kirmse, Wolfgang,Houk, K. N.
, p. 475 - 477 (2007/10/02)
Triplet arylcarbenes react intramolecularly with unsaturated ortho substituents, while singlet arylcarbenes react preferentially with solvent methanol.Rotation about the exocyclic C-CH bond is necessary in order for cycloaddition of the singlet carbene to
