117635-42-4Relevant academic research and scientific papers
Counterattack mode differential acetylative deprotection of phenylmethyl ethers: Applications to solid phase organic reactions
Chakraborti, Asit K.,Chankeshwara, Sunay V.
supporting information; experimental part, p. 1367 - 1370 (2009/07/04)
A counterattack protocol for differential acetylative cleavage of phenylmethyl ether has been developed. The phenylmethyl moiety is liberated as benzyl bromide that is isolated and reused providing advantages in terms of waste minimization/utilization and atom economy. The applicability of this methodology has been extended for solid phase organic reactions with the feasibility of reuse of the solid support.
Direct Conversion of Aryl Silyl Ethers to Alkyl Aryl and Diaryl Ethers
Saunders, D. G.
, p. 377 - 379 (2007/10/02)
The reaction of aryl silyl ethers with alkyl halide, or activated aryl halide, and tetrabutylammonium fluoride, yields alkyl aryl ethers or diaryl ethers, respectively.Alkyl silyl ethers under the same or related reaction conditions give mainly the corresponding alcohol, and only very low yields of the ether.
