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117637-79-3

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117637-79-3 Usage

General Description

Ethyl 3-iodo-1H-indole-2-carboxylate is a chemical compound that belongs to the family of indole carboxylates. It is a derivative of indole, which is a heterocyclic aromatic compound commonly found in some plants and perfumes. The presence of the ethyl and carboxylate groups in the compound gives it specific chemical and physical properties that make it potentially useful in organic synthesis and medicinal chemistry. The substitution of the 3-iodo group on the indole ring further enhances its reactivity, making it a valuable building block for the preparation of various pharmaceutical and agrochemical products. Ethyl 3-iodo-1H-indole-2-carboxylate is often used as a research reagent in the field of drug discovery and chemical biology due to its structural versatility and potential applications.

Check Digit Verification of cas no

The CAS Registry Mumber 117637-79-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,7,6,3 and 7 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 117637-79:
(8*1)+(7*1)+(6*7)+(5*6)+(4*3)+(3*7)+(2*7)+(1*9)=143
143 % 10 = 3
So 117637-79-3 is a valid CAS Registry Number.

117637-79-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name Ethyl 3-iodo-1H-indole-2-carboxylate

1.2 Other means of identification

Product number -
Other names ethyl 3-iodoindole-2-carboxylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:117637-79-3 SDS

117637-79-3Relevant articles and documents

Axially Chiral Aryl-Alkene-Indole Framework: A Nascent Member of the Atropisomeric Family and Its Catalytic Asymmetric Construction

Deng, Shuang,Jiao, Yinchun,Li, Tian-Zhen,Liu, Si-Jia,Shi, Feng,Wang, Cong-Shuai,Zhang, Yu-Chen

, p. 543 - 552 (2020)

A new class of axially chiral aryl-alkene-indole frameworks have been designed, and the first catalytic asymmetric construction of such scaffolds has been established by the strategy of organocatalytic (Z/E)-selective and enantioselective (4+3) cyclization of 3-alkynyl-2-indolylmethanols with 2-naphthols or phenols (all >95 : 5 E/Z, up to 98% yield, 97% ee). This reaction also represents the first catalytic asymmetric construction of axially chiral alkene-heteroaryl scaffolds, which will add a new member to the atropisomeric family. This approach has not only confronted the great challenges in constructing axially chiral alkene-heteroaryl scaffolds but also provided a powerful strategy for the enantioselective construction of axially chiral aryl-alkene-indole frameworks.

Synthesis and Reactivity of Oxazinoindolones via Regioselective 6-exo-dig Iodolactonization

Hammoud, Sokaina,Anselmi, Elsa,Cherry, Khalil,Kizirian, Jean-Claude,Thibonnet, Jér?me

, p. 6314 - 6327 (2018)

An efficient protocol for the facile construction of 3,4-dihydro-10-iodo-3-iodomethylene-[1,4]-oxazino[4,3-a]indol-1-ones has been developed by using a regio- and stereoselective iodolactonization reaction. Subsequent palladium cross-coupling reactions of 3,4-dihydro-10-iodo-3-iodomethylene-[1,4]-oxazino[4,3-a]indol-1-ones readily afforded functionalized oxazinoindolones.

Aryl halide and synthesis method and application thereof

-

Paragraph 0133-0135, (2020/06/02)

The invention discloses a synthesis method of aryl halides (including aryl bromide shown as a formula (2) and aryl iodide shown as a formula (3)). All the systems are carried out in an air atmosphere,visible light is utilized to excite a substrate or a photosensitizer to catalyze the reaction; and in a reaction solvent, when aromatic hydrocarbon shown in the formula (1) and sodium bromide serve as raw materials, aryl bromide shown in the formula (2) is obtained through a reaction under the auxiliary action of an additive (protonic acid); or when aromatic hydrocarbon shown in the formula (1) and sodium iodide are used as raw materials, under the auxiliary action of an additive (protonic acid), aryl iodide shown in the formula (3) is obtained through reaction. The synthesis method has the advantages of cheap and accessible raw materials, simple reaction operation and mild reaction conditions. The method is compatible with the arylamine which is liable to be oxidized. The invention provides a new method for the synthesis of aryl halides, realizes the amplification of basic chemicals aryl halides including aryl bromide shown in the formula (2) and aryl iodide shown in the formula (3),and has wide application prospect and practical value.

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