117668-70-9Relevant academic research and scientific papers
Catalytic enantioselective Amadori-Heyns rearrangement of racemic α-hydroxy ketones with arylamines: Synthesis of optically active α-arylamino ketones
Frongia, Angelo,Secci, Francesco,Capitta, Francesca,Piras, Pier Paolo,Sanna, Maria Luisa
supporting information, p. 8812 - 8814 (2013/09/24)
A novel synthesis of optically active α-arylamino ketones through an organocatalytic enantioselective Amadori-Heyns rearrangement is described. The Royal Society of Chemistry 2013.
Reduction of N-substituted 1-acetyl- and 1-benzoyl-ethanimines
Alcaide, Benito,Arjona, Odon,Pradilla, Roberto Fernandez de la,Plumet, Joaquin,Rodriguez-Campos, Ignacio M.,Santesmases, Maria J.
, p. 932 - 957 (2007/10/02)
The reduction of N-substituted 1-acetyl- and 1-benzoyl-ethanimines leads to aminoketones or aminoalcohols, depending upon the nature of the reducing agent employed.The reduction to aminoalcohols affords diastereomeric mixtures.A stereochemical pathway for
