117688-42-3

Basic information

• Product Name: N, N'-diisopropylpyrrolidine-1-carboximidamide
• Synonyms: N, N'-diisopropylpyrrolidine-1-carboximidamide
• CAS NO: 117688-42-3
• Molecular Weight: 197.324
• Mol File: 117688-42-3.mol

Chemical Properties

• CAS DataBase Reference: N, N'-diisopropylpyrrolidine-1-carboximidamide(CAS DataBase Reference)
• NIST Chemistry Reference: N, N'-diisopropylpyrrolidine-1-carboximidamide(117688-42-3)
• EPA Substance Registry System: N, N'-diisopropylpyrrolidine-1-carboximidamide(117688-42-3)

Safety Data

• Hazardous Substances Data: 117688-42-3(Hazardous Substances Data)

Upstream product

• 123-75-1 pyrrolidine 
• 68897-42-7 N′,N″-diisopropyl-N,N-dimethyl guanidine 

Relevant articles and documents

Titanacarborane mediated C-N bond forming/breaking reactions

Constrained-geometry titanacarboranes [σ:η1:η5-(OCH2)(R2NCH2)C2B9H9]Ti(NR2) (R = Me, Et) are synthesized via an unexpected reaction of [Me3NH][μ-7,8-CH2OCH2-7,8-C2B9H10] with Ti(NR2)4 (R = Me, Et), involving a C-O bond cleavage and C-N bond formation. These complexes can be readily converted to new amide species or alkoxide by reacting with amines or esters, respectively. Insertion of a series of unsaturated molecules into the Ti-N bond of the aforementioned complexes results in the formation of various half-sandwich titanacarboranes. [σ:η1:η5-(OCH2)(Me2NCH2)C2B9H9]Ti(NMe2) is also able to efficiently catalyze the hydroamination of carbodiimides and the transamination of guanidines. These results are summarized in this brief account.