117702-55-3Relevant academic research and scientific papers
Products and reaction pats in the liquid phase oxidation of trans-1,2-dichloroethene with oxygen
Griesbaum, Karl,Hayes, Michael P.,Werli, Vera
, p. 1366 - 1370 (2007/10/02)
Ultraviolet initiated liquid phase oxidation of neat trans-1,2-dichloroethene (1a) with oxigen at 30 deg C afforded ca. 45percent of the combined Cl-products CO, CO2, and phosgene as well as nine oxygenated and nine non-oxygenated chlorinated organic products.Major oxigenated products were cis- and trans-2,3-dichlorooxirane (6a, b) and 1,2,2-trichloroethyl formate (13); minor products were e.g., meso and rac bis(1,2,2-trichloroethyl)ether (11c, d) and dichloromethyl 1,2,2,-trichloroethyl ether (12).The mode of formation of all products is rationalized by a unified reaction scheme.
