117708-49-3

Upstream product

• 68737-75-7 1L-4-O-benzyl-myo-inositol 
• 108-24-7 acetic anhydride 
• 864951-05-3 (1R,2S,3S,4R)-2,3,4-tri-O-acetyl-1-O-benzylconduritol B 
• 6404-82-6 (+/-)-1,2-O-isopropylidene-myo-inositol 
• 87-89-8 D-myo-inositol 
• 26276-99-3 rac-1,4,5,6-tetra-O-benzyl-myo-inositol 
• 35949-67-8 (±)-1,4-di-O-benzyl-myo-inositol 
• 23486-90-0 (+/-) 1-O-benzyl-myo-inositol 

Downstream Products

• 23486-90-0 (+/-) 1-O-benzyl-myo-inositol 
• 5517-47-5 1⁽³⁾,2,4⁽⁶⁾,5,6⁽⁴⁾-penta-O-acetyl-sn-myo-inositol 
• 68737-75-7 1L-4-O-benzyl-myo-inositol 
• 5517-47-5 penta-O-acetyl myoinositol 
• 69256-52-6 L-myo-inositol 6-monophosphate 

Relevant academic research and scientific papers

Achieving molecular stability of racemic 4-O-benzyl-myo-inositol-1,3,5- orthoformate through crystal formation

Molecular stability of racemic 4-O-benzyl-myo-inositol-1,3,5-orthoformate, an early intermediate during the synthesis of phosphoinositols, depends on the phase in which it is stored. This orthoformate is stable when stored in the crystalline form or as solution in common organic solvents. The former has eluded chemists since the preparation of this benzyl ether two decades ago. The difficulty in obtaining crystals of this orthoformate is due to the cleavage of the orthoformate moiety during storage in the gummy state. Dimorphs (form I and form II) of crystalline racemic 4-O-benzyl-myo-inositol-1,3,5-orthoformate, were obtained when the gummy sample was stored over extended periods of time. Form I crystals could be obtained consistently, by crystallization of a frozen (-20 °C) solid sample, from a solution of dichloromethane-light petroleum. The two crystal forms display dissimilar patterns of hydrogen bonding and molecular assembly in the solid-state.

Flexible stereo- and regioselective synthesis of myo-inositol phosphates (Part 2): Via nonsymmetrical conduritol B derivatives

A practical route is described for the preparation of myo-inositol phosphates. Optically pure compounds can be prepared, in both forms, from p-benzoquinone by enzymatic resolution of a diacetoxyconduritol key intermediate. Monosubstituted inositol derivat

The synthesis and resolution of (+/-)-1,4-di-O-benzyl-2,3-O-isopropylidene-myo-inositol

An improved procedure for the preparation of 1,2-O-isopropylidene-myo-inositol is described.Racemic 1,4-di-O-benzyl-2,3-O-isopropylidene-myo-inositol was prepared by tin-mediated benzylation of 1,2-O-isopropylidene-myo-inositol and resolved readily by cry

The synthesis and resolution of (+/-)-1,5,6-tri-O-benzyl-myo-inositol

Racemic 1,5,6-O-benzyl-myo-inositol was prepared by five routes and converted into 1,5,6-tri-O-benzyl-2,3-O-isopropylidene-myo-inositol, the camphanates of which were readily separated by chromatography.The absolute configurations of the chiral derivative