117747-07-6Relevant academic research and scientific papers
THE CERIUM MEDIATED CONVERSION OF ESTERS TO ALLYLSILANES
Narayanan, B.A.,Bunnelle, W.H.
, p. 6261 - 6264 (1987)
Reaction of esters with the reagent prepared from CeCl3 and TMSCH2MgCl in THF, followed by deoxysilylation on silica gel, effects efficient conversion to allylsilanes.Methyl 1-adamantane carboxylate, a sterically hindered ester, does not react under these conditions.
