Tetrahedron Letters p. 6261 - 6264 (1987)
Update date:2022-08-11
Topics:
Narayanan, B.A.
Bunnelle, W.H.
Reaction of esters with the reagent prepared from CeCl3 and TMSCH2MgCl in THF, followed by deoxysilylation on silica gel, effects efficient conversion to allylsilanes.Methyl 1-adamantane carboxylate, a sterically hindered ester, does not react under these conditions.
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