117749-71-0Relevant academic research and scientific papers
Allyl Sulphide Synthesis by Phenylthio Migration: Relationship between Stereochemistry of Starting Materials and Regioselectivity of Double Bond Formation
Aggarwal, Varinder K.,Warren, Stuart
, p. 2579 - 2584 (2007/10/02)
Phenylthio migration to an alkyl migration terminus can be controlled to give mostly an allyl sulphide with a trisubstituted double bond and good E:Z selectivity but migration to a benzylic migration terminus is affected by stereochemistry: each diastereoisomer of the starting material preferentially forms one of two regioisomeric allylic sulphides.
