1178899-30-3Relevant academic research and scientific papers
Aromatic and benzylic C-H bond functionalization upon reaction between nitriles and perfluoroalkyl sulfoxides
Mace, Yohan,Urban, Celine,Pradet, Charlotte,Blazejewski, Jean-Claude,Magnier, Emmanuel
scheme or table, p. 5313 - 5316 (2010/02/27)
We studied the thermal behavior of some intermediates formed by reaction of nitriles with perfluoroalkyl sulfoxides upon trifluoromethanesulfonic anhydride activation. Bistriflate ketal 3, precursor of sulfilimine 1, may undergo a rearrangement to sulfany
Sulfilimines and sulfoximines by reaction of nitriles with perfluoroalkyl sulfoxides
Mace, Yohan,Urban, Celine,Pradet, Charlotte,Marrot, Jerome,Blazejewski, Jean-Claude,Magnier, Emmanuel
supporting information; experimental part, p. 3150 - 3153 (2009/12/07)
The species obtained by activation of perfluoroalkylated sulfoxides with trifluoromethanesulfonic anhydride behaves as highly electrophilic entities. Their reaction with nitriles allows a Ritter-like process leading to the new fluorinated acylsulfilimines
