117948-45-5Relevant academic research and scientific papers
Nitrosation of m-xylene, anisole, 4-nitrophenyl phenyl ether and toluene in trifluoroacetic acid or in acetic-sulfuric acid mixtures under nitric oxide
Atherton, John H.,Moodie, Roy B.,Noble, Darren R.,O'Sullivan, Brian
, p. 663 - 664 (1997)
Nitrosation in trifluoroacetic acid or in acetic-sulfuric acid mixtures is regioselective and accompanying non-selective nitrous acid catalysed nitration can be avoided by purging with nitric oxide.
Protonation and Acid Catalysed Hydrolysis of Nitrosoaryl Ethers
Moodie, Roy B.,O'Sullivan, Brian
, p. 205 - 208 (2007/10/02)
Studies of the equilibrium protonation and kinetics of acid catalysed hydrolysis of 4-nitrosoanisole, 4-nitrosophenyl phenyl ether and related compounds in dilute aqueous acid and in concentrated aqueous trifluoroacetic acid are reported.Hydrolysis is remarkably facile and occurs by nucleophilic attack of water at the ring carbon bearing the alkoxy or aryloxy substituent of the protonated nitroso aromatic.Direct and indirect pKa determinations for nitroso protonation are reported.
