117959-76-9

Upstream product

• 117959-77-0 <4aα,7aα(E)>-(+/-)-7a-(4,8-Dimethyl-3,7-nonadienyl)-4a,6,7,7a-tetrahydro-4-<3-(phenylmethoxy)propyl>-5H-2-pyrindine 
• 117959-74-7 <1α(R^*S^*),2α,2(E)>-(+/-)-2-(4,8-Dimethyl-3,7-nonadienyl)-2-(hydroxymethyl)-β-<3-(phenylmethoxy)propyl>cyclopentaneethanol 
• 64740-39-2 5-benzyloxypentanoic acid 
• 117959-71-4 5-Benzyloxy-1-pyrrolidin-1-yl-pentan-1-one 
• 117959-73-6 <4aβ,7aβ(E)>-(+/-)-7a-(4,8-Dimethyl-3,7-nonadienyl)hexahydro-4-<3-(phenylmethoxy)propyl>cyclopentapyran-3(1H)-one 
• 138336-58-0 <1α,1(E),2α(S^*)>-(+/-)-1-(4,8-Dimethyl-3,7-nonadienyl)-2-<4-(phenylmethoxy)-1-(1-pyrrolidinylcarbonyl)butyl>cyclopentanemethanol 
• 138383-33-2 (R)-5-Benzyloxy-2-[(1S,2R)-2-((E)-4,8-dimethyl-nona-3,7-dienyl)-2-hydroxymethyl-cyclopentyl]-1-pyrrolidin-1-yl-pentan-1-one 
• 118015-92-2 Methyl <1α,1(E),2α(S^*)>-(+/-)-1-(4,8-Dimethyl-3,7-nonadienyl)-2-<4-(phenylmethoxy)-1-(1-pyrrolidinylcarbonyl)butyl>cyclopentanecarboxylate 

Downstream Products

• 138336-59-1 C₃₂H₄₅NO₃ 
• 138458-92-1 C₂₉H₃₉NO 

Relevant academic research and scientific papers

Daphniphyllum Alkaloids. 11. Biomimetic Total Synthesis of Methyl Homosecodaphniphyllate. Development of the Tetracyclization Reaction

A biomimetic total synthesis of (+/-)-methyl homosecodaphniphyllate has been developed.The synthesis starts with a triply convergent, tandem Michael addition-enolate alkylation, wherein amide 9, enoate 7, and alkyl iodide 5 are assembled in essentially qu