118015-92-2

Upstream product

• 25662-28-6 1-(carboxymethoxy)cyclopentadiene 
• 22339-13-5 (E)-9-iodo-2,6-dimethylnona-2,6-diene 
• 117959-71-4 5-Benzyloxy-1-pyrrolidin-1-yl-pentan-1-one 

Downstream Products

• 117959-75-8 <1α(R^*S^*),2α,2(E)>-(+/-)-2-(4,8-Dimethyl-3,7-nonadienyl)-2-(formyl)-α-<3-(phenylmethoxy)propyl>cyclopentaneacetaldehyde 
• 117959-73-6 <4aβ,7aβ(E)>-(+/-)-7a-(4,8-Dimethyl-3,7-nonadienyl)hexahydro-4-<3-(phenylmethoxy)propyl>cyclopentapyran-3(1H)-one 
• 117959-76-9 (+/-)-17,18-Didehydro-23-(phenylmethoxy)-12,16-cyclo-1,12-secodaphnane 
• 117959-74-7 <1α(R^*S^*),2α,2(E)>-(+/-)-2-(4,8-Dimethyl-3,7-nonadienyl)-2-(hydroxymethyl)-β-<3-(phenylmethoxy)propyl>cyclopentaneethanol 
• 138336-59-1 C₃₂H₄₅NO₃ 
• 117959-77-0 <4aα,7aα(E)>-(+/-)-7a-(4,8-Dimethyl-3,7-nonadienyl)-4a,6,7,7a-tetrahydro-4-<3-(phenylmethoxy)propyl>-5H-2-pyrindine 
• 117959-78-1 (3α,3aβ,6α,6aα,9aR^*,10S^*)-(+/-)-2,3,3a,6,6a,7,8,9-Octahydro-10-methyl-10-(4-methyl-3-pentenyl)-6-<3-(phenylmethoxy)propyl>-3,6-methano-1H-dicyclopentapyridine 
• 138336-60-4 (+/-)-23-(Phenylmethoxy)-12,16-cyclo-1,12-secodaphnane 
• 138336-58-0 <1α,1(E),2α(S^*)>-(+/-)-1-(4,8-Dimethyl-3,7-nonadienyl)-2-<4-(phenylmethoxy)-1-(1-pyrrolidinylcarbonyl)butyl>cyclopentanemethanol 

Relevant academic research and scientific papers

Daphniphyllum Alkaloids. 11. Biomimetic Total Synthesis of Methyl Homosecodaphniphyllate. Development of the Tetracyclization Reaction

A biomimetic total synthesis of (+/-)-methyl homosecodaphniphyllate has been developed.The synthesis starts with a triply convergent, tandem Michael addition-enolate alkylation, wherein amide 9, enoate 7, and alkyl iodide 5 are assembled in essentially qu