117993-84-7Relevant academic research and scientific papers
Photochemical carbon skeletal rearrangement of the Baylis-Hillman products: β-C-H activation leading to furans
Matsumoto, Shoji,Mikami, Koichi
, p. 469 - 470 (1998)
Furan ring formation was found in photochemical reaction of the methyl ether of the Baylis-Hillman products. This reaction proceeds via β-C-H activation of the photo-excited carbonyl compounds.
[4+1]/[2+1] Cycloaddition reactions of fischer carbene complexes with α,β-unsaturated ketones and aldehydes
Barluenga, Jose,Fanlo, Hugo,Lopez, Salome,Florez, Josefa
, p. 4136 - 4140 (2008/02/14)
(Chemical Equation Presented) Put two and two together: Fischer carbene complexes and α,β-unsaturated carbonyl compounds smoothly react under thermal conditions to give 2,3-dihydrofurans, and from them furans or 1,4-dicarbonyl compounds were easily accessible (see scheme). This cycloaddition process involves a cyclopropanation reaction followed by rearrangement from the acylcyclopropane to a dihydrofuran.
THE CARBENE COMPLEX ROUTE TO DONOR-ACCEPTOR-SUBSTITUTED CYCLOPROPANES
Wienand, Anette,Reissig, Hans-Ulrich
, p. 2315 - 2318 (2007/10/02)
A variety of donor-acceptor-substituted cyclopropanes can be synthesized starting from electron deficient olefins in preparatively usefull yields employing Fischer carbene complexes as donor-carbene source.
