118034-57-4Relevant academic research and scientific papers
A simple method of regenerating areneruthenium dichloride dimers, 6-arene)>2, from their monomeric adducts with amines or tertiary phosphines, RuCl2(η6-arene)L
Pertici, Paolo,Bertozzi, Sergio,Lazzaroni, Raffaello,Vitulli, Giovanni,Bennett, Martin A.
, p. 117 - 122 (2007/10/02)
The monomeric amine or tertiary phosphine complexes RuCl2(η6-arene)L (arene=benzene, p-cymen) can be reconverted into their dimeric precursors 6-arene)>2 by heating with 1,5-cyclooctadiene (COD), 2-propanol, and anhydrous Na2CO3 and subsequent treatment of the resulting ruthenium(0) complexes Ru(η6-arene)(η4-COD) with HCl; the ligand L can be recovered.
