1180560-76-2Relevant academic research and scientific papers
α-Amido sulfones: Novel substrates for the concise synthesis of naturally occurring 2,6-disubstituted piperidine alkaloids
Das, Biswanath,Damodar, Kongara,Bhunia, Nisith
, p. 377 - 380 (2011/12/16)
Isosolenopsin and isosolenopsin A, two 2,6-dialkyl piperidine constituents of the venom of the fire ant of the genus Solenopsis have been synthesized in racemic form starting from α-amido sulfones involving Wittig olefination and reductive cyclization.
Gallium(III) chloride-catalyzed Sakurai reaction of α-amido sulfones with allyltrimethylsilane: Access to synthesis of 2,6-disubstituted piperidine alkaloid derivatives
Kumar, R. Sateesh Chandra,Reddy, G. Venkateswar,Babu, K. Suresh,Rao, J. Madhusudana
, p. 564 - 565 (2011/04/21)
The Sakurai reaction of N-alkoxycarbonylamino sulfones (α-amido sulfones) with allyltrimethylsilane in the presence of gallium(III) chloride (5 mol %) proceeded smoothly to afford the corresponding protected homoallylamines in high yields (82-96%). As an
